Neodymium(III) hydroxide

Neodymium(III) hydroxide
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.036.816
EC Number
  • 240-514-4
  • InChI=1S/Nd.3H2O/h;3*1H2/q+3;;;/p-3
    Key: ZBAQHMBLDSQPHC-UHFFFAOYSA-K
  • [Nd+3].[OH-].[OH-].[OH-]
Properties
Nd(OH)3
Molar mass 195.266
Appearance rose solid
Related compounds
Other anions
neodymium(III) oxide
Other cations
praseodymium(III) hydroxide
samarium(III) hydroxide
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Neodymium(III) hydroxide is an insoluble inorganic compound with the chemical formula Nd(OH)3.

Production

Neodymium(III) nitrate and ammonia water will react to produce neodymium(III) hydroxide

Nd(NO3)3 + 3 NH3·H2O → Nd(OH)3↓ + 3 NH4NO3

If the amount of Nd(NO3)3 is 40g/L, the amount of ammonia water needed is 0.50 mol/L. The ammonia water is mixed into the Nd(NO3)3 solution at the speed of 1.5mL/min, and polyethylene glycol is used to control pH. The process will produce neodymium(III) hydroxide powder with grain size ≤1μm.

Chemical properties

Neodymium(III) hydroxide can react with acid and produce neodymium salts:

Nd(OH)3 + 3 H+ → Nd3+ + 3 H2O

For example, to create neodymium acetate with neodymium(III) hydroxide:

Nd(OH)3 + 3CH3COOH → Nd(CH3COO)3 + 3H2O

See also