Mercury(II) nitrate

Mercury(II) nitrate
Names
IUPAC names
Mercury dinitrate
Mercury(II) nitrat
Other names
Mercuric nitrate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.030.126
EC Number
  • 233-152-3
PubChem CID
RTECS number
  • OW8225000
UNII
UN number 1625
  • InChI=1S/Hg.2NO3/c;2*2-1(3)4/q+2;2*-1 ☒
    Key: ORMNPSYMZOGSSV-UHFFFAOYSA-N ☒
  • InChI=1/Hg.2NO3/c;2*2-1(3)4/q+2;2*-1
    Key: ORMNPSYMZOGSSV-UHFFFAOYAS
  • [N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[Hg+2]
Properties
Hg(NO3)2
Molar mass 324.60 g/mol (anhydrous)
Appearance colorless crystals or white powder
Odor sharp
Density 4.3 g/cm3 (monohydrate)
Melting point 79 °C (174 °F; 352 K) (monohydrate)
soluble
Solubility soluble in nitric acid, acetone, ammonia
insoluble in ethanol
−74.0·10−6 cm3/mol
Hazards
GHS labelling:
GHS03: OxidizingGHS06: ToxicGHS08: Health hazardGHS09: Environmental hazard
Danger
H272, H300, H310, H330, H373, H410
NFPA 704 (fire diamond)
NFPA 704 four-colored diamondHealth 3: Short exposure could cause serious temporary or residual injury. E.g. chlorine gas Flammability 0: Will not burn. E.g. water Instability 1: Normally stable, but can become unstable at elevated temperatures and pressures. E.g. calcium Special hazard OX: Oxidizer. E.g. potassium perchlorate
3
0
1
Flash point Nonflammable
Safety data sheet (SDS) ICSC 0980
Related compounds
Other anions
Mercury(II) sulfate
Mercury(II) chloride
Other cations
Zinc nitrate
Cadmium nitrate
Related compounds
Mercury(I) nitrate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Infobox references

Mercury(II) nitrate is an inorganic compound with the formula Hg(NO3)2.xH2O. These colorless or white soluble crystalline salts are occasionally used as a reagent. It is made by treating mercury with hot concentrated nitric acid. Neither anhydrous nor monohydrate has been confirmed by X-ray crystallography. The anhydrous material is more widely used.

Uses

Mercuric nitrate has been used in mercuration of ketones. Mercuric nitrate was formerly used in carroting felt for hats.

Health information

Mercury compounds are highly toxic. The use of this compound by hatters and the subsequent mercury poisoning of said hatters is a common theory of where the phrase "mad as a hatter" came from.


See also